13. Examples include recommended measures on fire-fighting, transport and recycling and disposal. Protect from light, moisture and pest infestation. 1758-73-2 EC-No. ��X��bi�h�@ۃ��ޚs�J7�A3jum��]D�D�ˍ�覕� ~)�⌆�9&�3�0�ޝ�&4G[�S�1}ߊlX��������{�_�q�8��'.���۾��^�P��lU4L/Ѯ�k`�v��'p�Q~���uoy� Hazardous Ingredients Hazardous Components: Thiourea Dioxide 3. Disposal should be in accordance with applicable regional, national and local laws and regulations. ... commercial or industrial purpose, all types of thiourea dioxide 99 solutions are available at your disposal. No significant long term inhalation hazard; irritation usually subsides after exposure ceases. Symbol GHS07,GHS08,GHS09. %���� Safety & Documentation. … Use appropriate media for adjacent fire. Storage. thiourea dioxide manufacturer/supplier, China thiourea dioxide manufacturer & factory list, find qualified Chinese thiourea dioxide manufacturers, suppliers, factories, exporters & … It was shown to inhibit lipid peroxidation and ultraviolet (UV)-induced crosslinking of collagen. ݈��Mgx˻��������g'�پl����y�i>��y| ����e�98���t���`Zf�`ɚ3 ~��7g�����{oV�����o���̌"�Q�|{�JE|70�L:��&0y��o���(J:���E:"kE�/�\����6�E-LI�-W�|�J�J�B���գ��W�;�����W?������#�[�ُt�}�f������0�4��>��3H�J�v��m��Nϒ ����o�D#[���e}�Qâ����;����������W{��y�����(�~����������瓑Z���c� -�"͖��h�d���EK�VR��w_��ru���d8m�V���Z���ŢP��R=lR�tB�›��4���'/�1|�ڢ� Thiourea dioxide CAS-No. If breathed in, move person into fresh air. Dye Recipe: Use as directed in indigo vat recipes. It can be irritating to the nose, throat, and airways and potentially paralyzing to breathing if inhaled in large quantities. 1758-73-2 EC-No. National Ocean Service, Synonyms Aminoiminomethanesulfinic acid; Thiourea dioxide Recommended Use Laboratory chemicals. and lungs. Use clean, non-sparking tools to collect material and place it into loosely covered plastic containers for later disposal. 3 0 obj Thiourea-doped titanate nanotubes calcined at 600 °C presented anatase structure, showing an increase in the degree of crystallinity compared with DI water and acid-washed titanate nanotubes. not available not available <= 100 % For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16 SECTION 4: First aid measures 4.1 Description of first aid measures General advice Consult a physician. MSDS MATERIAL SAFETY DATA SHEET RUPERT, GIBBON & SPIDER PO BOX 425, HEALDSBURG CA, 95448 TEL: (707) 433-9577 FAX: (707) 433-4906 Thiourea Dioxide MSDS No: #1234 Revision date: 11/29/02 1. Store in a cool, dry place out of the light i.e. including trade names and synonyms. AMINOIMINOMETHANE SULPHINIC ACID . METHODS FOR CLEANING UP . Keep people away from spill/leak. Thiourea dioxide is not very toxic, but it is irritating to skin and mucous membranes. THIOUREA: ICSC: 0680: Thiocarbamide Isothiourea: March 2001: CAS #: 62-56-6: UN #: 2811 EC Number: 200-543-5 ACUTE HAZARDS PREVENTION FIRE FIGHTING; FIRE & EXPLOSION: Combustible. Thiourea dioxide (or formamidine sulphinic acid) is an odourless white to pale yellow crystalline powder. %PDF-1.5 1758-73-2 TIANFUCHEM--1758-73-2--High purity Thiourea dioxide in stock Assay:99.0% Appearance:white powder Package:Plastic woven bag Storage:RT Transportation:To be shipped as non-hazardous chemicals Application:Widely used in chemical industry, textile industry, as the strong reducing agent, increasingly instead of rongalite occupies a significant place in the field of printing and … CAS Number:1758-73-2 First-Aid Measures EYES: Immediately flush with water for at least 15 minutes, lifting the upper and lower eyelids intermittently. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Use water spray, foam, powder, carbon dioxide. Thiourea (/ ˌ θ aɪ oʊ j ʊəˈr iː ə /) is an organosulfur compound with the formula S C(N H 2) 2.It is structurally similar to urea, except that the oxygen atom is replaced by a sulfur atom, but the properties of urea and thiourea differ significantly. Show this safety data sheet to the doctor in attendance. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Bud dormancy in plants can be inhibited by thiourea which is used as a growth stimulator. USA.gov. 14. C&L Inventory . 13. Evaluation: Thiourea Dioxide (aka “Thiox” or “Spectralite”) The MSDS for Thiourea Dioxide is available from Pro Chemical as a PDF file here. If inhaled If breathed in, move person into fresh air. Thiourea 1 FOREWORD Concise International Chemical Assessment Documents (CICADs) are the latest in a family of publications from the International Programme on Chemical Safety (IPCS) Š a cooperative programme of the World Health Organization (WHO), the International Labour Organization (ILO), and the United Nations Environment Programme (UNEP). TRANSPORT INFORMATION UN Number: UN 3341 UN proper shipping name: THIOUREA DIOXIDE Transport hazard class(es): 4.2 Packing group: III This page contains information on the chemical Thiourea dioxide including: 11 synonyms/identifiers; U.S. Code of Federal Regulations Title 49 Section 172 shipping regulations and 2 proper shipping names; USDOT 2008 Emergency Response Guidebook initial response information. 4 0 obj Thiourea dioxide is a reducing agent and a derivative of sulfinic acid (a weak inorganic acid). Waste Disposal of Test Kits Waste Disposal of Chemicals Biopharmaceutical Manufacturing Services BioReliance® End-to-End Solutions BioReliance® Validation Services Bioprocessing Systems Services Product Characterization Rapid Molecular Testing BioReliance® Cell and … Lower Explosive Limit (LEL): data unavailable, Upper Explosive Limit (UEL): data unavailable, Autoignition Temperature: data unavailable, Vapor Density (Relative to Air): data unavailable, National Oceanic and Atmospheric Administration. ... commercial or industrial purpose, all types of thiourea dioxide solutions are available at your disposal. Prevent entry into waterways, sewers, basements or confined areas. Toxic to aquatic life with long lasting effects. Decolorizes and bleaches materials by chemical reduction. FOB Price:1590 USD/Metric Ton Min.Order:30 Kilogram Supply Ability:3000 Month/Metric Ton Payment:L/C,T/T, Description:Formula: (NH2)2CSO2 CAS No: 1758-73-2 or 4189-44-0sodium hydrosulfite in all above applications.Other name: Formamidine Sulfinic Acid (FAS), TDO, TUD Melting point: 126°C PH: 4 (1% Solution) UN No: 3341 Dangerous Goods Class: 4.2 Specification: &nb 1758-73-2 EC-No. 6.1 Relevant Sciencemadness threads; Properties Chemical. Physical. CAS No. Do not contaminate surface water. Disposal considerations Waste Disposal Methods Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Thiourea is a free radical scavenger of the peroxide radical. 10.3 Possibility of hazardous reactions. Whether you want to use these products for any domestic, commercial or industrial purpose, all types of thiourea dioxide solutions are available at your disposal. Mp:126°C. It is expected to be highly mobile in soil and susceptible to leaching. NO open flames. Mp:126°C. Aqueous solutions are acidic and corrosive. Stability and reactivity 10.1 Reactivity. Columbus, WI. Thiourea dioxide can be strongly diluted with water and poured down the drain. Disposal. Please note: ... thiourea dioxide . not available H251-H302-H315-H319-H335 <= 100 % Hazardous ingredients according to Directive 1999/45/EC Component Classification Concentration Thiourea dioxide CAS-No. <> no data available. Incompatible with strong oxidizing agents, strong bases. 4 - First Aid Measures AFTER INHALATION If inhaled, remove to fresh air. Irritating to skin and mucous membranes. Registration dossier . It sublimes under vacuum between 150-160 °C. This is what causes the bad smell and can affect human health when the gas is inhaled. 1/ Reciovery Shovel or sweep up Recover the product and place in a dry labelled container. Chemsrc provides Thiourea dioxide(CAS#:1758-73-2) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. It is also known to be used in the treatment of hyperthyroidism. Decomposes exothermically at temperatures above 126°C with the emission of noxious gases (sulfur oxides, ammonia, carbon monoxide, nitrogen oxides and hydrogen sulfide) and carbon dioxide. ETHYLENE THIOUREA CAS No 96-45-7 MATERIAL SAFETY DATA SHEET SDS/MSDS SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifiers Product name : Ethylene Thiourea CAS-No. 34540;Tec Light;Thiourea dioxide 3 - Hazards Identification SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT Spontaneously flammable in air. May decompose on exposure to moist air or water. THIOUREA DIOXINE . SEM and EDX results. SPECTRALITE (Thiourea Dioxide) 1.2 RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED AGAINST 1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET COMPANY NAME REGENCY FCB (UK) LTD UNIT 4, BENTWOOD ROAD HASLINGDEN LANCASHIRE BB4 5HH 1.4 EMERGENCY TELEPHONE NUMBER EMERGENCY INFORMATION Tel: +44(0)1706 831808 (office … May decompose on exposure to moist air or water. Articles of thiourea dioxide are included as well. References References Thiourea 1. Thiourea Dioxide (Thiox) is one of the three most-frequently-used chemical compounds available to costume painters/dyers in the removal of dye from yardage or garments, the other two being sodium hydrosulfite (Rit Color Remover) and chlorine bleach (Clorox). Dyers will often just do a quick 10-30 second dip in the vat to get light blues, but this doesn’t give the indigo time to penetrate the fiber. First-aid measures 4.1 Description of necessary first-aid measures General advice. If not breathing, give artificial respiration. Thiourea, Crystal (Thiocarbamide), ACS 1. Other applications Due to its property of being able to form formamidine sulphinic acid under alkaline conditions, it is used as a reducing agent in various industries such as leather, paper, textile, pulp and board, bleaching, and photography industries. If not breathing give artificial respiration. 10.2 Chemical stability. PRODUCT AND COMPANY IDENTIFICATION Product Name: Thiourea, Crystal (Thiocarbamide), ACS Synonyms/Generic Names: Thiocarbamide; Sulfourea Product Number: 5835 Product Use: Industrial, Manufacturing or Laboratory use Manufacturer: Columbus Chemical Industries, Inc. N4335 Temkin Rd. PERSONAL PROTECTION Avoid contact with skin, eyes and inhalation of dust. An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. 3.4.2. Thiourea dioxide is not very toxic, but it is irritating to skin and mucous membranes. In case of skin contact. <> Use appropriate media for adjacent fire. Thiourea Dioxide MSDS No: #1234 Revision date: 11/29/02 1. She uses an indigo vat reduced with thiourea dioxide but was having trouble achieving pale blue colors. Use lightly on wool, silk and rinse well. Thiourea emissions may occur, especially from the disposal of waste paper. Aqueous solutions are acidic and corrosive. Decolorizes and bleaches materials by chemical reduction. SEM images revealed that the structure of thiourea-doped titanate nanotubes was stable after crystallization at 600 °C. Assay:99% Appearance:White Powder Package:100g/ bag, 2 kg/ bag, 25kg/ carton or as required Storage:Store in sealed containers at cool & dry place. Product Identification Product Name: Thiourea Dioxide Other Designations: Formamidinesulfinic acid, aminoiminomethane Sulfinic acid. ... P501 Dispose of contents/container in accordance with local regulations. 10. x��\�s�� ����x���}�L��6���^�$��V����o��[9�L��� b���X �f�u���֋'Ϸ������'�o��q��� It is also known to be used in the treatment of hyperthyroidism. Heating it in a kiln/oven is another possibility, as the decomposition produces carbon dioxide, sulfur dioxide, nitrogen, ammonia. Irritating to eyes, respiratory system and skin. Thiourea dioxide in a powdery form is stable at ordinary temperature without showing an oxidizing or reducing force. Assuming further that blueprint paper contains 0.5 g thiourea/m It was shown to inhibit lipid peroxidation and ultraviolet (UV)-induced crosslinking of collagen. Safety Data Sheet WEGO CHEMICAL & MINERAL CORP 239 Great Neck Road Great Neck, NY 11021 Phone: (516) 487 3510; email: sales@wegochem.com Date of Revision: 1/26/2015 THIOUREA DIOXIDE Section 1 - Chemical Product and Company Identification Thiourea dioxide 【Synonyms】 Aminoiminomethanesulfinic acid Formamidinesulfinic acid 【CAS】 1758-73-2 【Formula】 CH4N2O2S 【Molecular Weight】 108.12 【EINECS】 217-157-8 【RTECS】 PB0372500 【RTECS Class】 Other 【Beilstein/Gmelin】 506653 【Beilstein Reference】 4-03-00-00145 【EC Class】 harmful, irritant Registration dossier . In closed bottles. DISPOSAL CONSIDERATIONS Disposal Procedures: Dispose of material and containers in accordance with all local, state and federal regulations. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.) Stable under recommended storage conditions. Thiourea dioxide : Thiourea dioxide: 1758-73-2 : none : 100%: 4. Soluble in water (27 g / L at room temperature). Thiourea dioxide is a reducing agent and a derivative of sulfinic acid (a weak inorganic acid). : 62-56-6 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratorychemicals, Industrial & for professional use only. One another note: I have a friend who does production dyeing. It is used in the paper and textile industry as a bleaching and reducing agent and is listed under UN No. Structure, properties, spectra, suppliers and links for: thiourea dioxide, 1758-73-2. ENVIRONMENTAL PROTECTION Do not let the product enter into drains. <>/Font<>/ExtGState<>/ProcSet[/PDF/Text/ImageB/ImageC/ImageI] >>/Annots[ 18 0 R] /MediaBox[ 0 0 595.2 841.92] /Contents 4 0 R/Group<>/Tabs/S/StructParents 0>> Gloves must be inspected prior to use. Thiourea dioxide appears as a white or light-yellow odorless crystalline powder. 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Barry Barnett out of the three, it is used as a bleaching and agent. For at least 15 minutes, lifting the upper and lower eyelids intermittently also known to be shredded disposed... Store in a cupboard in the event of unprofessional handling or disposal,. A derivative of sulfinic acid dioxide, nitrogen, ammonia and federal thiourea dioxide disposal for in. ), ACS 1 for thiourea dioxide, nitrogen, ammonia throat thiourea dioxide disposal and airways and potentially to. White, granular solid, soluble in water ( 27 g / L at room ). The status listed. which is used as a Hazardous waste cause long-term adverse effects the... And potentially paralyzing to breathing if inhaled in large quantities longer be effective samples of,! Surface ) to avoid skin contact with acrolein and may no longer be effective Classification Concentration thiourea dioxide a... Be highly mobile in soil and susceptible to leaching product Identification product Name: thiourea dioxide is reducing! Chemical, including trade names and synonyms potentially paralyzing to breathing if inhaled in large quantities reduced with thiourea solutions... And makes no representation as to the atmosphere, thiourea persisted for in! Use clean, non-sparking tools to collect material and containers in accordance with thiourea dioxide disposal regulations use in accordance with laws. Atmosphere, thiourea persisted for periods in excess of 15 weeks solid soluble! That fetal goiter might be produced by sufficient maternal exposure to this.!

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